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8.3 Flammable Solids

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The OSHA Laboratory Standard defines a flammable solid as a “solid, other than a blasting agent or explosive, that is liable to cause fire through friction, absorption of moisture, spontaneous chemical change, or retained heat from manufacturing or processing, or which can be ignited readily and when ignited, burn so vigorously and persistently to create a serious hazard.” An example of a flammable solid is gun powder.

Under the DOT hazard class system, flammable solids are listed as hazard class 4. Flammable solids are further broken down into three subcategories:

  • Flammable Solids – Class 4.1
  • Spontaneously Combustible – Class 4.2
  • Dangerous When Wet – Class 4.3
  • Many of the same principles for handling and storage of flammable liquids apply to flammable solids. Always keep flammable solids stored away from oxidizers, and away from heat or ignition sources such as radiators, electric power panels, etc.
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